Er, sonicated in acetone for 30 min, then washed with deionized bonding, isopropyl alcohol prior to the Cu oxidation; thus, acetic acid For CNT u water and it was important to minimizeelectrochemical hemical reaction. remedy was employed. The significant to reduce Cu oxidation; for that reason, acetic acid therapy bonding, it was 4-aminophenyl diazonium JNJ-54861911 supplier cations generated in situ by the reaction of pphenylenediamine and NaNO2 in an acidic medium had been utilised as the precursor, which was employed. The 4-aminophenyl diazonium cations generated in situ by the reaction were recognized to cut down and NaNO reactive radical capable of bonding to metal surfaces of p-phenylenediamine to a highly 2 in an acidic medium had been utilised because the precursor, (Figure 2A) [591]. For CNT-Pt a extremely reactive radical was electrochemically metal which have been known to reduce to bonding, ethylenediaminecapable of bonding to grafted around the (Figure 2A) acetonitrile CNT-Pt bonding, ethylenediamine by electrochemically surfacesPt surface in [591]. For as a solvent comparable to that reportedwas Segut et al. (Figure 2B) [62]. Herlem et al. has acetonitrile as a solvent comparable to that reported by Segut et al. grafted around the Pt surface inused a comparable electrochemical grafting reaction to modify metal electrodes [62]. Herlem et al. has employed Cyclic voltammetry at a grafting reaction s-1 (Figure 2B) with ethylenediamine [63,64]. a related electrochemicalscan price of 50 mVto was employed to electrodes with ethylenediamine [63,64]. Cyclic voltammetry at a scan price modify metal determine the oxidative grafting of ethylenediamine on a Pt sheet electrode in acetonitrile was used to determine the oxidative grafting of ethylenediamine on a Pt sheet of 50 mV s-1with an Ag pseudo-reference electrode (Figure S1).electrode in acetonitrile with an Ag pseudo-reference electrode (Figure S1).Figure 2. Proposed mechanism for the chemical bond formation between metals and open-ended CNTs. (A) In situ Figure two. and attachment of an for the chemical bond to a Cu surface and subsequent bonding to CNTs. (A) In situ generation Proposed mechanism amine functional group formation in between metals and open-ended a carboxylic acid generation and attachment of of CNT. functional group to a Cu surface and subsequent a Pt surface and subsequent functional group in the open end anaamine (B) Electrochemical attachment of ethylenediamine tobonding to a carboxylic acid functional group at the open carboxylic acid (B) Electrochemical attachment of ethylenediamine to a Pt surface and bonding of your amine end towards the end of a CNT. in the open ends with the CNTs. subsequent bonding from the amine finish to the carboxylic acid in the open ends of your CNTs.Subsequently, the amine-grafted metal surface and carboxylic-functionalized HD-CNT Subsequently, amine-grafted metal surface and carboxylic-functionalized HDcross-section within the film had been clamped collectively and heated to 80 C to promote a CNT cross-section inside the film weregroups [14]. reaction between the surface functional clamped with each other and heated to 80 to promote a reaction involving the surface functional groups [14]. 2.four. CNTs Bonded to Metal as a Working Electrode 2.4. ElectrochemicalMetal as a Working and electrical conductivity measurements with the CNTs Bonded to (R)-(+)-Citronellal Cancer characterization Electrode chemically bonded CNTs to Cu metal have been performed conductivity measurements of your Electrochemical characterization and electrical on electrodes assembled as shown in Figure S2.bon.
